Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)
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چکیده
In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen)(H(2)O)(2)](+) coordination cation, one half of a C(2) symmetric [Fe(CN)(6)](3-) anion and disordered methanol and ethanol solvent mol-ecules that are equally populated at two different sites. The Mn(III) atom chelated by the 3-Meosalophen ligand adopts a slightly distorted MnN(2)O(4) octa-hedral geometry with the coordination completed by two water mol-ecules. The [Mn(3-Meosalophen)(H(2)O)(2)](+) cations, [Fe(CN)(6)](3- )anions and solvent mol-ecules are connected into a zigzag chain through hydrogen-bonding inter-actions.
منابع مشابه
Diaqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ2 O,N,N′,O′}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate
In the cation of the title compound, [Mn(C(18)H(18)N(2)O(4))(H(2)O)(2)]ClO(4)·0.5C(12)H(24)O(6)·H(2)O, the Mn(III) ion is coordinated by two water O atoms, and two O atoms and two N atoms from the tetradentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]di-phenolate ligand, completing a distorted octa-hedral geometry. One O atom of the 18-crown-6-ether is disordered over two ...
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